Computer modeling of radical copolymerization under unusual conditions
نویسندگان
چکیده
منابع مشابه
Experimental observation of crossover from noncondensed to counterion condensed regimes during free radical polyelectrolyte copolymerization under high-composition drift conditions.
By combining detailed online kinetics of comonomer consumption with light scattering, viscosity, and conductivity data, experimental detection of changing degrees of counterion condensation was achieved by using comonomers of widely separated reactivity ratios that produced large composition drifts during synthesis. Endproducts of such syntheses contained mixtures of chains of widely varying li...
متن کاملProtodecarboxylation of benzoic acids under radical conditions.
A new approach to protodecarboxylation is described that enhances the substrate scope for benzoic acids. The reaction uses oxidative radical conditions to decarboxylate a variety of acids in acetonitrile.
متن کاملModeling of lmmunosensors under Nonequilibrium Conditions
In an attempt to optimize immunosensors operating with an immobilized antibody as binding protein and an analyte-enzyme conjugate as signal generator that is signitlcantly larger in molecular size than the analyte, in a previous communication (Part I) (S.-H. Paek and W. Schramm (1991) Anal. Biochem. 196) we developed mathematical models for the prediction of performance characteristics. These m...
متن کاملUnusual truncation of N-acylated peptoids under acidic conditions.
The terminal amino groups of peptoids have often been protected with acetyl groups to improve cell permeability and therapeutic potential, and to prevent the poisoning of the catalysts in organometallic reactions. Interestingly, the unusual truncation of the terminal peptoid unit has sometimes been encountered when the acetylated linear peptoids were treated with a TFA cleavage cocktail. In thi...
متن کاملComputer Aided Molecular Modeling Of Membrane Metalloprotease
Molecular modeling is a set of computational techniques for construction of 3D structure of a protein especially membrane bound proteins whose structures can not be elucidated using experimental techniques. These techniques has been applied in the study of membrane metalloproteases for comparing wild and mutated enzymes, docking inhibitors in the catalytic site and examination of binding pocket...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 2004
ISSN: 0887-624X,1099-0518
DOI: 10.1002/pola.20451